Reported that at least two powerful rockets of the Libyan leader large Bab al-Azizia made early compound on Monday.
Three TV stations was shortly after the explosions.
The blasts to the largest, Tripoli has so far taken, said correspondents. NATO is Col Gaddafi's forces as he tried to suppress a revolt.
The BBC's Ian Pannell in Tripoli said the damaged buildings seemed the same that used peace Col Gaddafi to host a recent visit by a mission of the African Union.
Libyan television and the Jamahiriya and Shababiya said reports were TV stations off air for over half an hour after the blasts.
On Sunday the Libyan leader forces bombarded areas of the Western City of Misurata loyal, despite saying it had stopped attacks allow local tribes to negotiate with rebels.
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Ian Pannell, BBC News, TripoliShortly after midnight, there were at least two huge explosions in the capital.
The objective seems to have been office building that form part of Col Gaddafi's connection. The devastation is blown out with walls, roofs collapsed and debris over a wide area distributed.
Smoke rose from the destroyed buildings as the firefighters sprayed foam on the rubble. Some officials at the scene said there were some injuries, others opposed that.
NATO says it is active targeting command and positions, but it is impossible to know whether this site had a military purpose. There certainly seem to be not too obvious signs of it.
For supporters of the rally on the ruins of this regime was a personal attack against Col Gaddafi himself and they promised to remain to leave on the website despite NATO warnings.
At least six people were reported killed in the latest bombing, which allegedly hit the city centre and three residential area.A prisoners soldiers Pro-Gaddafi news agency AFP said that the battle for Misurata would lose loyalist troops.
"Many soldiers give up they want to, but have fear of running [by rebels]," Lili Mohammed said one was Mauritanian against the insurgents.
On Sunday, said Libyan Deputy Foreign Minister Khaled Kaim which army was, to the local tribes, the battle to "peaceful and not military" rules allow.
But Col Omar Bani, military spokesman for the rebel Transitional National Council (TNC), Col Gaddafi said "A really dirty game played in an attempt to divide his opponents".
"It is a trick, they did not go," Col Bani said in the eastern city of Benghazi. "they have street a little bit of Tripoli they stayed but ready to attack again."
OrbitingBritish journalist James Hider, which is for the newspaper the times in Misratah, told the BBC, although Pro-Gaddafi forces encircled Misratah, their forces within the city were surrounded by rebel fighters.
Supporters chanted defiance from the ruins of a building by the air strikes hit the Col GaddafiHe said their supplies were cut off and the main force outside the city of supplies from elsewhere were NATO air strikes are starving.
Mr Hider said rebels hope she would be able, once again the control of the city centre but do not believe, she would be able, all of the Government forces defeat strikes until NATO destroyed their biggest weapons.
Human rights groups say more than 1,000 people were killed in Misratah and many more injured. Ships have the wounded to hospitals in Benghazi utility helicopter was.
The revolt against Col Gaddafi began in February, inspired by uprisings elsewhere in the Arab world.
Rebel leader received a financial boost on Sunday when Kuwait announced that it was 50 m type dinar (￡ 110 m, $180 m) of the Transitional National Council.
Air raids on Libyan State is NATO troops under a UN mandate for the protection of civilians carried out.
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